Synthesis And Characterization Of Nanocellulose/Zif-8 Composite Aerogel
Tajimova Gulistan Raman qizi , PhD student, Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, Uzbekistan Kuzieva Makhliyo Mukhammadievna , PhD, Junior researcher, Institute of Polymer Chemistry and Physics, Academy of Sciences of the Republic of Uzbekistan, Uzbekistan Abdumutolib Abdupatto o‘g‘li Atakhanov , Doctor of technical sciences, Professor, Director of Institute of Polymer Chemistry and Physics, Academy of Sciences of the Republic of Uzbekistan, Uzbekistan Adizov Bobirjon Zamirovich , Doctor of technical sciences, Professor, Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, Uzbekistan Khomidov Fakhriddin Gafurovich , Doctor of Chemical Sciences, Institute of General and Inorganic Chemistry of Academy of Sciences of the Republic of Uzbekistan, Termez State University of Engineering and Agrotechnologies, UzbekistanAbstract
In this study, a nanocellulose and ZIF-8 composite aerogel was successfully synthesized via an in-situ growth method. The structural and elemental properties of the obtained hybrid aerogel were investigated using FTIR and EDX/XRF analyses. FTIR results confirmed the presence of characteristic functional groups belonging to both nanocellulose and ZIF-8, indicating successful integration of the metal–organic framework into the cellulose matrix. EDX/XRF analysis revealed distinct zinc-related peaks corresponding to Zn Kα and Zn Kβ emissions, confirming the incorporation of ZIF-8 particles within the porous aerogel structure. The obtained results demonstrated the successful formation of a stable hybrid porous material.
Keywords
Nanocellulose, ZIF-8, composite aerogel, in-situ synthesis
References
Pierre A.C., Pajonk G.M. Chemistry of aerogels and their applications // Chemical Reviews. – 2002. – Vol. 102, No. 11. – P. 4243–4265. DOI: 10.1021/cr0101306.
Kistler S.S. Coherent expanded aerogels and jellies // Nature. – 1931. – Vol. 127. – P. 741. DOI: 10.1038/127741a0.
Hüsing N., Schubert U. Aerogels – airy materials: chemistry, structure, and properties // Angewandte Chemie International Edition. – 1998. – Vol. 37, No. 1–2. – P. 22–45. DOI: 10.1002/(SICI)1521-3773(19980202)37:1/2<22::AID-ANIE22>3.0.CO;2-I.
Aegerter M.A., Leventis N., Koebel M.M. Aerogels Handbook. – New York: Springer, 2011. – 978 p. DOI: 10.1007/978-1-4419-7589-8.
Maleki H. Recent advances in aerogels for environmental remediation applications: A review // Chemical Engineering Journal. – 2016. – Vol. 300. – P. 98–118. DOI: 10.1016/j.cej.2016.04.098.
Lavoine N., Bergström L. Nanocellulose-based foams and aerogels: processing, properties, and applications // Journal of Materials Chemistry A. – 2017. – Vol. 5, No. 31. – P. 16105–16117. DOI: 10.1039/C7TA02807E.
Chen Y., Zhang L., Yang Y., Pang B., Xu W., Duan G., Zhang X., Jiang S. Recent progress on nanocellulose aerogels: preparation, modification, composite fabrication, applications // Advanced Materials. – 2021. – Vol. 33, No. 11. – P. 2005569. DOI: 10.1002/adma.202005569.
Rafieian F., Hosseini M., Jonoobi M., Yu Q. Development of hydrophobic nanocellulose-based aerogel via chemical vapor deposition for oil separation for water treatment // Cellulose. – 2018. – Vol. 25, No. 8. – P. 4695–4710. DOI: 10.1007/s10570-018-1882-9.
Zu G., Shen J., Zou L., Wang F., Wang X., Zhang Y., Yao X. Nanocellulose-derived highly porous carbon aerogels for efficient adsorption of organic pollutants // Carbon. – 2016. – Vol. 99. – P. 203–211. DOI: 10.1016/j.carbon.2015.12.002.
Wang J., Zhang Y., Zhang S., Song J. Functional nanocellulose-based aerogels for environmental remediation // ACS Sustainable Chemistry & Engineering. – 2020. – Vol. 8, No. 24. – P. 8944–8960. DOI: 10.1021/acssuschemeng.0c02147.
Isogai A., Saito T., Fukuzumi H. TEMPO-oxidized cellulose nanofibers // Nanoscale. – 2011. – Vol. 3, No. 1. – P. 71–85. DOI: 10.1039/C0NR00583E.
Furukawa H., Cordova K.E., O’Keeffe M., Yaghi O.M. The chemistry and applications of metal-organic frameworks // Science. – 2013. – Vol. 341, No. 6149. – P. 1230444. DOI: 10.1126/science.1230444.
Zhao S., Malfait W.J., Guerrero-Alburquerque N., Koebel M.M., Nyström G. Biopolymer aerogels and foams: chemistry, properties, and applications // Angewandte Chemie International Edition. – 2018. – Vol. 57, No. 26. – P. 7580–7608. DOI: 10.1002/anie.201709014.
Lavoine N., Bergström L. Nanocellulose-based foams and aerogels: processing, properties, and applications // Journal of Materials Chemistry A. – 2017. – Vol. 5, No. 31. – P. 16105–16117. DOI: 10.1039/C7TA02807E.
Isogai A., Saito T., Fukuzumi H. TEMPO-oxidized cellulose nanofibers // Nanoscale. – 2011. – Vol. 3, No. 1. – P. 71–85. DOI: 10.1039/C0NR00583E.
Wang J., Zhang Y., Zhang S., Song J. Functional nanocellulose-based aerogels for environmental remediation // ACS Sustainable Chemistry & Engineering. – 2020. – Vol. 8, No. 24. – P. 8944–8960. DOI: 10.1021/acssuschemeng.0c02147.
Maleki H. Recent advances in aerogels for environmental remediation applications: A review // Chemical Engineering Journal. – 2016. – Vol. 300. – P. 98–118. DOI: 10.1016/j.cej.2016.04.098.
Rafieian F., Hosseini M., Jonoobi M., Yu Q. Development of hydrophobic nanocellulose-based aerogel via chemical vapor deposition for oil separation for water treatment // Cellulose. – 2018. – Vol. 25, No. 8. – P. 4695–4710. DOI: 10.1007/s10570-018-1882-9.
Zu G., Shen J., Zou L., Wang F., Wang X., Zhang Y., Yao X. Nanocellulose-derived highly porous carbon aerogels for efficient adsorption of organic pollutants // Carbon. – 2016. – Vol. 99. – P. 203–211. DOI: 10.1016/j.carbon.2015.12.002.
Download and View Statistics
Copyright License
Copyright (c) 2026 Tajimova Gulistan Raman qizi, Kuzieva Makhliyo Mukhammadievna, Abdumutolib Abdupatto o‘g‘li Atakhanov, Adizov Bobirjon Zamirovich, Khomidov Fakhriddin Gafurovich

This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors retain the copyright of their manuscripts, and all Open Access articles are disseminated under the terms of the Creative Commons Attribution License 4.0 (CC-BY), which licenses unrestricted use, distribution, and reproduction in any medium, provided that the original work is appropriately cited. The use of general descriptive names, trade names, trademarks, and so forth in this publication, even if not specifically identified, does not imply that these names are not protected by the relevant laws and regulations.

Applied Sciences
| Open Access |
DOI: