Applied Sciences | Open Access | DOI: https://doi.org/10.37547/tajas/Volume08Issue01-11

The Adsorptive Purification Of Low-Quality Glycerin By Biocarbon Adsorbents

Salikhanova Dilnoza Saidakbarovna , Doctor of Technical Sciences, Senior Researcher, Institute of General and Inorganic Chemistry of the Academy of Sciences of the Republic of Uzbekistan, Uzbekistan
Savrieva Dilafruz Doutovna , Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, Uzbekistan
Ismailova Mukhtasar Abdumutalib kizi , PhD, Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, Uzbekistan
Sagdullaeva Dilafruz Saidakbarovna , Doctor of Technical Sciences, Senior Researcher, Institute of Bioorganic Chemistry of the Academy of Sciences of the Republic of Uzbekistan, Uzbekistan
Abdurakhimov Akhror Anvarovich , Doctor of Technical Sciences, Tashkent Chemical-Technological Institute, Uzbekistan
Karabaeva Muslima Iftikhorovna , Doctoral candidate (DSc), International Institute of Food Technologies and Engineering, Uzbekistan

Abstract

This study investigates the purification of low-quality glycerin using biocarbon adsorbents derived from cherry pits. The carbon adsorbent produced (ACCP) demonstrated superior efficacy in reducing glycerin color, decreasing it from 10 mg I/100 cm³ to 5 mg I/100 cm³, outperforming the imported coconut carbon adsorbent (ACC), which only achieved a reduction to 6 mg I/100 cm³. It has also been established that a carbon adsorbent with a particle size of 2-3 mm is considered optimal, as smaller particles hinder filtration, thereby increasing ash content due to the migration of fine carbon particles into the filtrate. A reduction in the acid number by 5-6 times allows for an improvement in the quality of glycerin and extends its shelf life. It has been determined that the carbon adsorbent derived from cherry pits selectively reduces the amount of free fatty acids. Initial glycerin parameters corresponded to grade T-88 specifications; however, after treatment with the synthesized adsorbents, the parameters improved to meet the D-98 standard requirements. These findings suggest that cherry pit-based adsorbents are a promising alternative for purifying glycerin in various industrial applications.

Keywords

Glycerin, adsorbent, impurities

References

Nevolin, F. V. (1954). Chemistry and Technology of Glycerin Production. Moscow: Pishchepromizdat.

Gavrilko, N. P., Klimenko, N. G., & Ikhno, N. P. (1976). Purification of technical fats before hydrolysis using surfactants. Oil and Fat Industry, (2), 57.

Zhukov, A. V., Arbitman, S. P., & Fedotov, N. M. (1969). Filter perlite powder and its application in the sugar industry. Moscow, 42.

Irodov, M. V., & Eliseeva, N. S. (1965). Organic contaminants in glycerin. Oil and Fat Industry, (10), 24–26.

Wang, Y., Xiao, Y., & Xiao, G. (2019). Sustainable value-added C3 chemicals from glycerol transformations: A mini-review for heterogeneous catalytic processes. Chinese Journal of Chemical Engineering, 27, 1536–1542. https://doi.org/10.1016/j.cjche.2019.03.001

Azelee, N. I. W., Ramli, A. N. M., Manas, N. H. A., Salamun, N., Man, R. C., & El Enshasy, H. (2020). Glycerol in food, cosmetics, and pharmaceutical industries: Basics and new applications. International Journal of Science and Technology Research, 8(12), 553–558.

Kaur, J., Sharma, A. K., Jha, M. K., & Gera, P. (2020). Valorisation of crude glycerol to value-added products: Perspectives on process technology, economics, and environmental issues. Biotechnology Reports, 27, 1–23. https://doi.org/10.1016/j.btre.2020.00014

Barbosa, S. L., et al. (2020). Preparation of activated charcoal from Acrocomia aculeata for purification of pretreated crude glycerol. Biomass Conversion and Biorefinery, 1–9. https://doi.org/10.1007/s13399-020-00745-7

Kumar, L. R., Yellapu, S. K., Tyagi, R. D., & Zhang, X. (2019). A review on variation in crude glycerol composition, bio-valorization of crude and purified glycerol as a carbon source for lipid production. Bioresource Technology, 293, 1–11. https://doi.org/10.1016/j.biortech.2019.122155

Lopez, J. M., et al. (2022). A theoretical and experimental study of liquid-liquid equilibrium to refine raw glycerol obtained as a byproduct of biodiesel production. Chemical Engineering Journal Advances, 10, 1–13. https://doi.org/10.1016/j.ceja.2022.100257

Sinaga, M. S., Ramadhan, M. R., Rico, G., & Sitompul, W. G. T. (2019). Effect of acidification mole ratio and solvent volume ratio on glycerol purification. IOP Conference Series: Materials Science and Engineering, 505, 1–5. https://doi.org/10.1088/1757-899X/505/1/012116

Raman, A. A. A., Tan, H. W., & Buthiyappan, A. (2019). Two-step purification of glycerol as a value-added byproduct from the biodiesel production process. Frontiers in Chemistry, 7, 774. https://doi.org/10.3389/fchem.2019.00774

Leshchenko, N. F. (1979). Study and development of technology for the adsorptive purification of distilled glycerin and the separation of adsorbents. Dissertation for the Candidate of Technical Sciences, Krasnodar, 99–105.

Bochkine, S. I. (2008). Production of Glycerin. Leningrad, 64.

Guidelines for Research Methods, Technological Control, and Accounting in the Oil and Fat Industry. (1967). Leningrad: VNIIZH, (Vol. 2), 245–258.

GOST 6824-96. (1996). Distilled Glycerin. Minsk, 17.

Savrieva, D. D., Salikhanova, D. S., Eshmetov, I. D., Abdurakhimov, A. A., & Agzamova, F. N. (2018). Production of selective carbon adsorbents for the selective purification of distilled glycerin. Chemical Technology, Control and Management, (3), 16–19.

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Salikhanova Dilnoza Saidakbarovna, Savrieva Dilafruz Doutovna, Ismailova Mukhtasar Abdumutalib kizi, Sagdullaeva Dilafruz Saidakbarovna, Abdurakhimov Akhror Anvarovich, & Karabaeva Muslima Iftikhorovna. (2026). The Adsorptive Purification Of Low-Quality Glycerin By Biocarbon Adsorbents . The American Journal of Applied Sciences, 8(01), 124–129. https://doi.org/10.37547/tajas/Volume08Issue01-11