CARBON NANOSPHERE SYNTHESIZED FROM MAIZE COB-HAIR FOR ARSENIC ADSORPTION FROM WATER
Jayashri Shukla , Department of Chemistry, K. M. Agrawal College, Kalyan 421301, Maharashtra, India Suman Tripathi , Department of Chemistry, K. M. Agrawal College, Kalyan 421301, Maharashtra, India Anuradha Pandey Dubey , Sharon Institute of Nanotechnology, Parishkar College of Global Excellence (Autonomous), Jaipur, Rajasthan, India Madhuri Sharon , Sharon Institute of Nanotechnology, Parishkar College of Global Excellence (Autonomous), Jaipur, Rajasthan, IndiaAbstract
Carbon Nanospheres (CNS) are synthesized by pyrolyzing Maize cob-hair using the CVD method for two hours, at 10000C in presence of Ni, Fe, or Co nanometals as the catalyst. The morphology of carbon nanomaterial was characterized by the HRSEM images. The XRD pattern and the Raman spectrum confirmed the graphitic nature of the carbon. Surface area measurement of CNM was done by the Methylene Blue test method. The impact of catalyst was noted on the surface area of the carbon nanosphere; the maximum being 95.018 m2/g when Fe nanoparticle was used as catalyst, 83.141 m2/g when Ni was used, and a minimum of 21.379 m2/g in presence of Co. These carbon nanospheres were used for Arsenic adsorption from water. Adsorption of Arsenic was assessed by Chand Pasha et al’s method. It was found that after 12 hrs of exposure, CNS with 95 m2/g surface area could adsorb 32% arsenic; CNS (of 23.8m2/g surface area adsorbed 31% whereas CNS (surface area of 21.379m2/g. could adsorb only 16% arsenic. The arsenic adsorption capacity was found to be affected by the available surface area.
Keywords
Maize cob-hair, carbon nanosphere, chemical vapor deposition
References
Kong J, Franklin NR, Zhou C, Chapline MG, Peng S, Cho K, Dai H. Nanotube Molecular Wires as Chemical Sensors. Science, 287(5453), 622-625, 2000.
Ijima Sumio, Helical microtubules of graphitic carbon, Nature (London), 354,56-58, 1991.
Ando Y, Iijima S. Preparation of carbon nanotubes by arc-discharge evaporation. Jpn. J. Appl. Phys., 32, L107 – L109, 1993.
Hernadi K, Fonseca A,Nagy JB, Bernaerts D,RigaJ,Lucas A. Catalytic synthesis and purification of carbon nanotubes. Synthetic Metals.77(1–3), 31-34,1996
Satishkumar BC, Govindaraj A, Rao CNR. Bundles of aligned carbon nanotubes obtained by the pyrolysis of ferrocene–hydrocarbon mixtures: role of the metal nanoparticles produced in situ. Chemical Physics Letters.307(3–4), 158-162, 1999.
Dai H, FranklinN, Han J. Exploiting the properties of carbon nanotubes for nanolithography. J. Appl. Phys. Lett., 73(11), 1508, 1998.
Satishkumar BC, Govindaraj A, Sen R, Rao CNR. Single-walled nanotubes by the pyrolysis of the acetylene-organometallic mixture. Chemical Physics Letters. 293(1–2), 47-52, 1998
Hafner J H, Bronikowski MJ, Bobak R. A, Nikolaev P, Rinzler A G, Colbert D T, Smith KA, Smalley RE. Catalytic growth of single-wall carbon nanotubes from metal particles. Chemical Physics Letters, 296(1–2), 195-202, 1998
Kong J, Cassell AM, Hongjie D. Chemical vapor deposition of methane for single-walled carbon nanotubes. Chemical Physics Letters.292(4–6), 567-574,1998
Mukhopadhyay, Krishna KM, Maheshwar Sharon. Fullerenes from camphor: A natural source. Phys. Rev. Lett. 72, 3182-3185, 1994
Mukhopadhyay K, Sharon Maheshwar. Glassy carbon from camphor — a natural source. Materials Chemistry and Physics. 49(2), 105-109, 1997.
Mukhopadhyay K, Krishna KM, Maheshwar Sharon. A simple method and a new source for getting diamond-like carbon film and polycrystalline diamond film. Materials Chemistry and Physics 49 (3), 252-257, 1997
Sharon Maheshwar ,Sundarakoteeswarana N, Kichambare PD, Kumar M, Zhao X. Semiconducting carbon films from a natural source: camphor.
Diamond and Related Materials. 8(2–5), 485-489, 1999
Pradhan D, Sharon Maheshwar. Carbon nanotubes, nanofilaments, and nanobeads by a thermal CVD process. Mat. Sci. Engg. B, 96,24-28, 2002
Sharon Maheshwar, Mukhopadhyay K, Yase K, Iijima S, Ando Y, Zhao X. Spongy carbon nanobeads—A new material. Carbon. 36(5–6), 507-511, 1998.
Pasha Chand, Badiyadka Narayana.Determination of Arsenic in Environmental and Biological Samples Using Toluidine Blue or Safranine O by Simple Spectrophotometric Method. Bulletin of Environmental Contamination and Toxicology 81(1):47-51, 2008. DOI: 10.1007/s00128-008-9454-1
Shukla Jayashri, Ph.D. Thesis, Role of raw material composition in yielding carbon nano material by Carbon Vapour Deposition and study the uptake of arsenic dissolved in water by carbon nano material, Solapur University, Solapur, 2012.
Suman Tripathi, Maheshwar Sharon, Maldar NN, Shukla Jayashri, Madhuri Sharon. Nanocarbon synthesis using plant oil and differential responses to various parameters optimized using the Taguchi method. Carbon Letters. 14(4), 210-217, 2013. DOI: http://dx.doi.org/DOI:10.5714/CL.2013.14.4.210
Ansari R, Sadegh M. Application of Activated Carbon for Removal of Arsenic Ions from Aqueous Solutions. E-Journal of Chemistry. 4(1),103-108, 2007.
Ghanizadeh G, Ehrampoush MH, MT. Application of iron impregnated activated carbon for removal of arsenic fromwater.2010. Article retrieved from http://journals.tums.ac.ir/upload_files/aip/pdf/16 4.pdf
Naghizadeh Ali. Comparison between activated carbon and multiwall carbon nanotubes in the removal of cadmium(II) and chromium(VI) from water solutions. Journal of Water Supply: Research and Technology-Aqua. 64 (1) 64–73, 2015. https://doi.org/10.2166/aqua.2014.022
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