Joint Synthesis Of Acetone And Acetaldehyde From Acetylene

Kenzhebek Akmalaiuly; Fayzullaev Normurot Ibodullaevich; Karjavov Abdikhakim Rahmonovich

doi:10.37547/tajet/Volume02Issue09-20

Articles | Open Access | DOI: https://doi.org/10.37547/tajet/Volume02Issue09-20

Joint Synthesis Of Acetone And Acetaldehyde From Acetylene

Kenzhebek Akmalaiuly , Doctor Of Technical Sciences, Professor, Kazakh National Research Technical University Named After K.I.Satpayev (Satbayev University), Uzbekistan
Fayzullaev Normurot Ibodullaevich , Doctor Of Technical Sciences, Professor, Samarkand State University, Uzbekistan
Karjavov Abdikhakim Rahmonovich , Samarkand State University, Uzbekistan

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Published Date 2020-09-29

Pages 109-119

Abstract

The study investigated the possibility of using catalysts based on compounds of cadmium, zinc and other elements filled with orbital electrons d10, having several polyfunctional properties, as well as promoted by compounds of various metals in the hydration reaction of acetylene and its derivatives. The acetylene hydration reaction yields acetaldehyde or acetone depending on the composition and nature of the catalyst used under the same conditions. In particular, the formation of acetylene at 360-440 0C in the presence of a catalyst from cadmium fluoride-containing 20% CdF2, 5.0% AlF3, 75% Al2O3: acetaldehyde formation when reacted with water = 1: 3-1: 5, cadmium fluoride, It has been found that using catalysts containing zinc, iron, nickel, cobalt compounds instead of aluminium fluoride, the process leads to the formation of acetone.

Keywords

Acetylene, , acetone,

References

Lebedev N.N. (1988). Chemistry and technology of the main organic and petrochemical synthesis. Textbook for universities. 4th ed. Moscow. Chemistry, p. 592.

Timofeev B.C., Serafimov L.A. & Tymoshenko A.B. (2010). Principles of the technology of basic organic and petrochemical synthesis: a textbook for universities. Ed. 3rd, rev. and add. Moscow. High school, p. 408.

Fayzullayev, N., Akmalaiuly, K., & Karjavov, A. (2020). Catalytic synthesis of a line by acetylene hydration. News of the National Academy of Sciences of the Republic of Kazakhstan, Series chemistry and technology, 2(440), 23-30.

Fayzullaev, N. I., Yusupov, D., & Umirzakov, R. R. (2001). Catalytic synthesis of acetone by direct hydration of acetylene. Uzbekistan kimyo magazines. N5. http://sersc.org/journals/index.php/IJAST/article/view/13765

Omanov, B. S., Fayzullaev, N. I., Musulmonov, N. K., Xatamova, M. S., & Asrorov, D. A. (2020). Optimization of Vinyl Acetate Synthesis Process. International Journal of Control and Automation, 13(1), 231-238.

Fayzullaev, N.I., & Fozilov, S.F. (2019). Heterogeneous catalytic synthesis of vinyl acetate from acetylene. Scientific Aspect, 8 (1), 973-976.

Fayzullaev, N. I., Karjavov, A. R., & Yusupova, S. S. (2020). Catalytic Synthesis of Acetone Direct Acetylene Hydration. International Journal of Advanced Science and Technology, 29(05), 4507-4514.

Omanov, B. S., Fayzullaev, N. I., & Xatamova, M. S. (2020). Vinyl Acetate Production Technology. International Journal of Advanced Science and Technology, 29(3), 4923-4930.

Fayzullayev, N., Akmalaiuly, K., & Karjavov, A. (2020). Catalytic synthesis of a line by acetylene hydration. News of the National Academy of Sciences of the Republic of Kazakhstan, Series chemistry and technology, 2(440), 23-30.

Omanov, B. S., Fayzullayev, N. I., & Xatamova, M. S. (2019). VINYLACETATE Production Out of ACETYLENE. International Journal of Advanced Research in Science, Engineering and Technology, 6(12).

Fayzullaev, N. I., Yusupov, D., & Shirinov, X. Sh., Korotoev, AV., Umirzakov, RR.(2002). Catalytic vaporphase hydration of acetylene and its derivatives. Chemical Industry. N, 7, 1-33.

Fayzullaev, N. I., Sarimsakova, N. S., & Bakieva, H. A. (2018). Method of obtaining vinyl chloride and chloroprene from acetylene. Young Scientist, (24), 273-275.

Fayzullaev, N. I., Jumanazarov, R. B., Norkulov, U. M., & Omanov, B. Sh. (2018). Compact technology of vinyl acetate production. Scientific journal of SamSU.

Fayzullayev, N. I., & Turobjonov, S. M. (2015). Catalytic Aromatization of Methane. International Journal of Chemical and Physical Science, 4, 27-34.

Karjavov, A. R., Fayzullayev, N. I., & Musulmonov, N. X. (2020). Jointly Catalytic Synthesis of Vinyl Chloride and Chloroprene from Acetylene. International Journal of Control and Automation, 13(4), 55-62.

Omanov, B. S., Fayzullayev, N. I., & Xatamova, M. S. (2020). Catalytic synthesis of acetylene ut of vynil acetate and texture characteristics of catalysts. Asian Journal of Multidimensional Research (AJMR). Special Issue, March, 157-164.

Omanov, B. Sh. U., & Fayzullaev, N. I. (2020). Parameters of the technological mode of vinyl acetate synthesis. Universum: chemistry and biology, (4 (70)).

Fozilov, S.F., Faizullaev, N.I., & Sodikova, M.M. (2019). Catalytic vapor phase hydration of acetylene. Scientific Aspect, 8 (1), 976-979.

Sh, S. B. (2018). Rakhmatov Sh. B., Fayzullayev NI High silicon zeolite preparation from kaolin. Scientific journal of SamSU, 5(109), 106-111.

Fayzullaev, N. I., & Sh, S. B. (2018). Catalytic aromatization of methane with non-mo-contained catalysts. Austrian Journal of Technical and Natural Sciences, (7-8).

Fayzullaev, N. I., & Shukurov, B. S. (2017). Kinetics and Mechanism of the Reaction of Catalytic Dehydroaromatization of Methane. International Journal of Oil, Gas and Coal Engineering, 5(6), 124.

Fayzullaev, N. I., Jumanazarov, R. B., & Turabjanov, S. M. (2015). Heterogeneous Catalytic Synthesis of Vinylchloride by Hydrochlorination of Acetylene. IJISET-International Journal of Innovative Science, Engineering & Technology, 2(9).

Faizullaev, N.I., Kurbanov, A.M., & Doskazieva, G. Sh. (2016). Vapor-phase catalytic synthesis of acetone from acetylene. In Achievements, problems and prospects for the development of the oil and gas industry. pp. 468-474.

Fayzullaev, N., Akmalayuly, K., & Khakimov, F. (2020). Co-production of vinyl chloride and chloroprene from acetylene. Collection of scientific works, ΛΌГOΣ, 129-133.

Faizullaev, N., Saginaev, A., Shukurov, B., & Holliyev, Sh. (2020). Catalytic dehydroaromatization of associated petroleum gas. Collection of Science Works ΛΌГOΣ, 122-126.

Fayzullaev, N., Akmalayuly, K., & Khakimov, F. (2020). New nanocatalyst for the synthesis of acetone. Collection of Science Practices, ΛΌГOΣ, 126-129.

Akmalayev, K., Fayzullaev, N., & Khakimov, F. (2020). Heterogeneous catalytic synthesis of vinyl chloride from acetylene. Collection of Science Works, ΛΌГOΣ, 113-115.

Fayzullaev, N, Akmalayuly, K, & Khakimov, F (2020). Catalytic synthesis of vinyl acetate by acetylation of acetylene in the vapor phase. Zbіrnik naukovykh prats ΛΌГOΣ, 118-122.

Fayzullaev, N., Akmalayuly, K., & Khakimov, F. (2020). Heterogeneous catalytic synthesis of vinyl chloride and chloroprene by acetylene hydrochlorination. Collection of scientific works, ΛΌГOΣ, 115-118.

Omanov, B. S., Ibodullayevich, F. N., Anorboevich, E. K., & Sattorovna, K. M. (2020). Production of vinyl acetate from acetylene. ACADEMICIA: An International Multidisciplinary Research Journal, 10(6), 1031-1038.

Fayzullaev, N. I., Akmalaev, K. A., Karjavov, A., Akbarov, H. I., & Qobilov, E. (2020). Vapor phase catalytic hydratation of acetylene. ACADEMICIA: An International Multidisciplinary Research Journal, 10(7), 88-98.

Fayzullayev, N. I. (2019). Kinetics and mechanism of the reaction of the catalytic oxycondensation reaction of methane. Austrian Journal of Technical and Natural Sciences, (5-6).

Rakhmatov, S. B., & Fayzullaev, N. I. (2019). Technology for the production of ethylene by catalytic oxycondensation of methane. European Journal of Technical and Natural Sciences, (5-6), 44-49.